Synthetic Route of 513-74-6,Some common heterocyclic compound, 513-74-6, name is Ammonium carbamodithioate, molecular formula is CH6N2S2, traditional synthetic route has been very mature, but the traditional synthetic route has various shortcomings, such as complicated route, low yield, poor purity, etc, below Introduce a new synthetic route.
0.69g Ammonium dithiocarbamate were dissolved in 10ml MeOH and 1.47g 4-(2- bromoacetyl)-1-methylpyridinium bromide were added. After 2h at ambient temperature the mixture was refluxed. After cooling the precipitate was filtered, washed with MeOH and dried. Yield: 0.15g 1H-NMR (DMSO-d6) delta 4.32(s, 3H), 8.32(s, 1 H), 8.45(d,2H; J=6.9Hz), 9.08(d,2H; J=6.8Hz), 14.1 (br s, 1 H) 13C-NMR (DMSO-c/6) delta 47.3, 121.6, 122.5, 136.6, 141.3, 145.9, 190.2
These compound has a wide range of applications. It is believed that with the continuous development of the source of the synthetic route Ammonium carbamodithioate, its application will become more common.
Reference:
Patent; SANDOZ AG; KREMMINGER, Peter; STURM, Hubert; WO2013/34718; (2013); A1;,
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