Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 657-27-2, Name is L-Lysine monohydrocholoride, molecular formula is C6H15ClN2O2, belongs to amides-buliding-blocks compound. In a document, author is Zhang Xinming, introduce the new discover, SDS of cas: 657-27-2.
Cyclobutane-based peptides/terpyridine conjugates: Their use in metal catalysis and as functional organogelators
Two new conjugates, hcptpyDP and hcptpyTP, of a terpyridine derivative incorporating artificial peptide moieties, have been synthesized and their use in the preparation of metal catalysts and organogelators has been investigated. Ru(II) complexes derived from these ligands showed electrochemical behavior and activity as catalysts in the epoxidation of olefins similar to that of Beller’s catalyst. As organogelators, these conjugates were able to gelate a variety of solvents, from toluene to methanol, with satisfactory mgc (minimum gelation concentration) values. The presence of 4′-(4-carboxy)phenylterpyridine (hcptpy) moiety allows tuning the gelling properties and also influences the supramolecular self-assembling mode to produce chiral aggregates with respect to parent peptides DP and TP. In the case of the conjugates, pi-pi interactions provided by the aromatic moieties cooperate with inter-molecular hydrogen bonding between NH and CO in the amide groups. Further properties of peptide/terpyridine conjugates are under investigation in view of future applications. (C) 2018 Elsevier Ltd. All rights reserved.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 657-27-2. SDS of cas: 657-27-2.