Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology. 6893-26-1, Name is (R)-2-Aminopentanedioic acid, molecular formula is , belongs to amides-buliding-blocks compound. In a document, author is Nigiz, Filiz Ugur, Recommanded Product: (R)-2-Aminopentanedioic acid.
Treatment of the readily accessible spiro-cyclohexadienones from the PhI(OCOCF3)(2)-mediated spiro-cyclization of N-substituted benzanilides, with BF3 center dot Et2O initiates a tandem ring opening/closure reaction leading to the formation of the biologically interesting 8-hydroxy-phenanthridin-6(5H)-one compounds. This unique rearrangement pattern involves the ‘migration’ of the electron-deficient N-methyl carbamoyl moiety rather than the electron-rich aryl group as observed and reported previously in all other similar transformations.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 6893-26-1, in my other articles. Recommanded Product: (R)-2-Aminopentanedioic acid.
Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics