The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. Product Details of 1185-53-1, 1185-53-1, Name is Tris hydrochloride, SMILES is OCC(CO)(N)CO.[H]Cl, in an article , author is Sun, Jia, once mentioned of 1185-53-1.
Hydroxamic acids have attracted significant attention due to their widespread use in applied chemistry. In this report, a modified Angeli-Rimini method has been achieved via the visible light-mediated catalytic transformation of a variety of heterocyclic, aromatic and aliphatic aldehydes 1a-j to their corresponding hydroxamic acids 2a-j in 81-93% yield. The unique ability of vitamin K-3 as a photoredox catalyst to expedite the development of completely new reaction mechanisms and to enable the construction of challenging carbon-nitrogen bonds has been investigated. It is shown for the first time that the vitamin K-3 and aldehyde are largely responsible for rapid in situ reduction of Ag+ ions to catalytic photoluminescent Ag nanoclusters that possess a bandgap energy of 2.87eV and are less than 2 nm in size. A mechanism for this reaction has been proposed and is supported by UV-Vis, TEM, ESI/MS, FT-IR, H-1 NMR and C-13 NMR analyses. The investigated method utilizes readily available reagents and produces the hydroxamic acids in high yields without the formation of side products, making it simple, practical and cost-effective.
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Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics