Let’s face it, organic chemistry can seem difficult to learn, HPLC of Formula: https://www.ambeed.com/products/101187-40-0.html, Especially from a beginner’s point of view. Like 101187-40-0, Name is tert-Butyl (2-(2-(2-(2-aminoethoxy)ethoxy)ethoxy)ethyl)carbamate, molecular formula is amides-buliding-blocks, belongs to amides-buliding-blocks compound. In a document, author is Liu, Lu, introducing its new discovery.
A unified total synthesis of stemoamide-type alkaloids is reported. Our synthetic approach features the chemoselective convergent assembly of five-membered building blocks via stemoamide as the common precursor to tetracyclic natural products. The synthesis consists of two successive coupling reactions of the three five-membered building blocks. The first coupling reaction is the vinylogous Michael addition/reduction sequence, which enables the gram-scale synthesis of stemoamide. The second coupling reaction is a chemoselective nucleophilic addition to stemoamide. While the lactone-selective nucleophilic addition to stemoamide affords saxorumamide and isosaxorumamide, the lactam-selective reductive nucleophilic addition leads to the formation of stemonine. Both chemoselective nucleophilic additions enable direct modification of stemoamide, resulting in highly concise and efficient total syntheses of the stemoamide-type alkaloids.
If you are hungry for even more, make sure to check my other article about 101187-40-0, HPLC of Formula: https://www.ambeed.com/products/101187-40-0.html.
Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics