Chemistry Milestones Of Diphenylmethanamine

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Recommanded Product: Diphenylmethanamine. Joseph, D; Park, MS; Lee, S in [Joseph, Devaneyan; Park, Myeong Seong; Lee, Sunwoo] Chonnam Natl Univ, Dept Chem, Gwangju 61186, South Korea published Metal-free transamidation of benzoylpyrrolidin-2-one and amines under aqueous conditions in 2021.0, Cited 39.0. The Name is Diphenylmethanamine. Through research, I have a further understanding and discovery of 91-00-9.

N-Acyl lactam amides, such as benzoylpyrrolidin-2-one, benzoylpiperidin-2-one, and benzoylazepan-2-one reacted with amines in the presence of DTBP and TBAI to afford the transamidated products in good yields. The reactions were conducted under aqueous conditions and good functional group tolerance was achieved. Both aliphatic and aromatic primary amines displayed good activity under metal-free conditions. A radical reaction pathway is proposed.

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Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics