Recently I am researching about CHEMOSELECTIVE HYDROGENATION; SELECTIVE HYDROGENATION; EFFICIENT HYDROGENATION; CATALYTIC-HYDROGENATION; PD NANOPARTICLES; OXIDE CATALYSTS; UNIQUE APPROACH; PERFORMANCE; REDUCTION; MECHANISM, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21636010, 21878342]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2018M643001]; Hunan Provincial Natural Science Foundation of ChinaNatural Science Foundation of Hunan Province [2019JJ50758]; Hunan Provincial Science and Technology Plan Project, China [2019TP1001]; Postdoctoral Science Foundation of Central South University [205440]; Fundamental Research Funds for Central Universities of Central South University [CX20190097]; State Key Laboratory of Powder Metallurgy, Central South University, Changsha, China. Formula: C8H11NO. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Zhang, GJ; Tang, FY; Wang, XY; An, P; Wang, LQ; Liu, YN. The CAS is 104-10-9. Through research, I have a further understanding and discovery of 2-(4-Aminophenyl)ethanol
It is a persistent target to develop noble-metal-free catalysts that can achieve chemoselective hydrogenation of nitro compounds under mild reaction conditions. In this work, we report a new strategy for preparation of hydrogenation catalysts containing both CoNx and CoyZnS supported on N-doped porous carbon (CoNx-CoyZnS@NPC-Z). The CoNx-CoyZnS@NPC-Z catalysts were prepared by pyrolyzing the protein-metal-ion networks, followed by treatment with acid. We found that CoNxCoyZnS@NPC-3 catalyst delivers high catalytic activity and selectivity, affording almost full conversion and >98% selectivity in water/methanol mixture solvents at 90 degrees C under 5 bar of H-2 pressure for 3 h of reaction. Notably, the catalytic hydrogenation can work even under 1 bar of H-2 pressure and at room temperature with high conversion and selectivity. Besides, CoNx-CoyZnS@NPC-3 exhibits remarkable tolerance to CO or H2S poisoning and acid erosion.
Formula: C8H11NO. About 2-(4-Aminophenyl)ethanol, If you have any questions, you can contact Zhang, GJ; Tang, FY; Wang, XY; An, P; Wang, LQ; Liu, YN or concate me.
Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics