Category: amides-buliding-blocks. Cabre, A; Cabezas-Gimenez, J; Sciortino, G; Ujaque, G; Verdaguer, X; Lledos, A; Riera, A in [Cabre, Albert; Cabezas-Gimenez, Juanjo; Verdaguer, Xavier; Riera, Antoni] Inst Res Biomed IRB Barcelona, Baldiri Reixac 10, Barcelona 08028, Spain; [Cabre, Albert; Cabezas-Gimenez, Juanjo; Verdaguer, Xavier; Riera, Antoni] Univ Barcelona, Dept Quim Inorgan & Organ, Seccio Organ, Marti i Franques 1, E-08028 Barcelona, Spain; [Sciortino, Giuseppe; Ujaque, Gregori; Lledos, Agusti] Univ Autonoma Barcelona, Dept Quim, Edifici Cn, Cerdanyola Del Valles 08193, Spain; [Sciortino, Giuseppe] Univ Sassari, Dipt Chim & Farm, Via Vienna 2, I-07017 Sassari, Italy published Mild Iridium-Catalysed Isomerization of Epoxides. Computational Insights and Application to the Synthesis of beta-Alkyl Amines in 2019.0, Cited 58.0. The Name is Diphenylmethanamine. Through research, I have a further understanding and discovery of 91-00-9.
The isomerization of epoxides to aldehydes using the readily available Crabtree’s reagent is described. The aldehydes were transformed into synthetically useful amines by a one-pot reductive amination using pyrrolidine as imine-formation catalyst. The reactions worked with low catalyst loadings in very mild conditions. The procedure is operationally simple and tolerates a wide range of functional groups. A DFT study of its mechanism is presented showing that the isomerization takes place via an iridium hydride mechanism with a low energy barrier, in agreement with the mild reaction conditions.
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Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics