Get Up to Speed Quickly on Emerging Topics:Diphenylmethanamine

Bye, fridends, I hope you can learn more about C13H13N, If you have any questions, you can browse other blog as well. See you lster.. Formula: C13H13N

Formula: C13H13N. I found the field of Chemistry very interesting. Saw the article Mild Iridium-Catalysed Isomerization of Epoxides. Computational Insights and Application to the Synthesis of beta-Alkyl Amines published in 2019.0, Reprint Addresses Verdaguer, X; Riera, A (corresponding author), Inst Res Biomed IRB Barcelona, Baldiri Reixac 10, Barcelona 08028, Spain.; Verdaguer, X; Riera, A (corresponding author), Univ Barcelona, Dept Quim Inorgan & Organ, Seccio Organ, Marti i Franques 1, E-08028 Barcelona, Spain.; Lledos, A (corresponding author), Univ Autonoma Barcelona, Dept Quim, Edifici Cn, Cerdanyola Del Valles 08193, Spain.. The CAS is 91-00-9. Through research, I have a further understanding and discovery of Diphenylmethanamine.

The isomerization of epoxides to aldehydes using the readily available Crabtree’s reagent is described. The aldehydes were transformed into synthetically useful amines by a one-pot reductive amination using pyrrolidine as imine-formation catalyst. The reactions worked with low catalyst loadings in very mild conditions. The procedure is operationally simple and tolerates a wide range of functional groups. A DFT study of its mechanism is presented showing that the isomerization takes place via an iridium hydride mechanism with a low energy barrier, in agreement with the mild reaction conditions.

Bye, fridends, I hope you can learn more about C13H13N, If you have any questions, you can browse other blog as well. See you lster.. Formula: C13H13N

Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics