An article Enantioselective reduction of N-alkyl ketimines with frustrated Lewis pair catalysis using chiral borenium ions WOS:000471721700018 published article about HETEROCYCLIC CARBENE LIGANDS; H BOND ACTIVATION; ASYMMETRIC HYDROGENATION; B(C6F5)(3)-CATALYZED HYDROSILATION; BORANE; IMINES; ACIDITY; HYDROSILYLATION; POLYMERIZATION; BORYLATION in [Mercea, Dan M.; Howlett, Michael G.; Piascik, Adam D.; Scott, Daniel J.; Ashley, Andrew E.; Fuchter, Matthew J.] Imperial Coll London, Mol Sci Res Hub, Dept Chem, White City Campus,Wood Lane, London W12 0BZ, England; [Steven, Alan] AstraZeneca PT&D, Charter Way, Macclesfield SK10 2NA, Cheshire, England in 2019.0, Cited 54.0. The Name is Diphenylmethanamine. Through research, I have a further understanding and discovery of 91-00-9. Formula: C13H13N
Enantioselective reduction of ketimines was demonstrated using chiral N-heterocyclic carbene (NHC)-stabilised borenium ions in frustrated Lewis pair catalysis. High levels of enantioselectivity were achieved for substrates featuring secondary N-alkyl substituents. Comparative reactivity and mechanistic studies identify key determinants required to achieve useful enantioselectivity and represent a step forward in the further development of enantioselective FLP methodologies.
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Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics