Artigas, Albert; Castanyer, Cristina; Roig, Nil; Lledo, Agusti; Sola, Miquel; Pla-Quintana, Anna; Roglans, Anna published an article in 2021. The article was titled 《Synthesis of Fused Dihydroazepine Derivatives of Fullerenes by a Rh-Catalyzed Cascade Process》, and you may find the article in Advanced Synthesis & Catalysis.Recommanded Product: 70-55-3 The information in the text is summarized as follows:
A synthetic methodol. was reported that functionalizes C60 and C70 fullerenes with dihydroazepine rings by a cascade reaction encompassing a rhodium-catalyzed cycloisomerization of 1,5-bisallenes and a [4+2] cycloaddition This transition metal-catalyzed cascade reaction provided a versatile and step-economical approach to the synthesis of 6,7-membered polyheterocyclic fullerene adducts. Electrochem. characterization of the products obtained ventures their application in organic and perovskite photovoltaic devices.4-Methylbenzenesulfonamide(cas: 70-55-3Recommanded Product: 70-55-3) was used in this study.
4-Methylbenzenesulfonamide(cas: 70-55-3) belongs to anime. Hydrogen peroxide (H2O2) and peroxy acids generally add an oxygen atom to the nitrogen of amines. With primary amines, this step is normally followed by further oxidation, leading to nitroso compounds, RNO, or nitro compounds, RNO2. Secondary amines are converted to hydroxylamines, R2NOH, and tertiary amines to amine oxides, R3NO.Recommanded Product: 70-55-3
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics