Nishimura, Kazuki’s team published research in Synlett in 2022-04-30 | CAS: 343338-28-3

Synlett published new progress about 1,3-Dipolar cycloaddition reaction, stereoselective. 343338-28-3 belongs to class amides-buliding-blocks, name is (S)-2-Methylpropane-2-sulfinamide, and the molecular formula is C4H11NOS, Product Details of C4H11NOS.

Nishimura, Kazuki published the artcileThorpe-Ingold Effect on High-Performance Chiral π-Copper(II) Catalyst, Product Details of C4H11NOS, the main research area is dimethylpyrazole preparation enantioselective.

The Thorpe-Ingold effect was applied to the design of a chiral ligand of π-copper(II) catalysts for the enantioselective α-fluorination of 1-(3,5-dimethyl-pyrazol-1-yl)-2-phenyl-ethanone, and also for the enantioselective Mukaiyama-Michael, Diels-Alder, and 1,3-dipolar cycloaddition reactions of N-acryloyl-3,5-dimethylpyrazoles I (R = Bn, ethynyl, ethenyl, etc.). The use of β,β-dimethyl-β-arylalanine-type ligand gave desired products e.g., II with higher enantioselectivity compared to with previously reported β-arylalanine-type ligands.

Synlett published new progress about 1,3-Dipolar cycloaddition reaction, stereoselective. 343338-28-3 belongs to class amides-buliding-blocks, name is (S)-2-Methylpropane-2-sulfinamide, and the molecular formula is C4H11NOS, Product Details of C4H11NOS.

Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics