Singh, Santosh K. published the artcileIdentification of Elusive Keto and Enol Intermediates in the Photolysis of 1,3,5-Trinitro-1,3,5-Triazinane, Recommanded Product: N-Methylformamide, the main research area is elusive keto enol intermediate photolysis trinitrotriazinane.
Enols have emerged as critical reactive intermediates in combustion processes and in fundamental mol. mass growth processes in the interstellar medium, but the elementary reaction pathways to enols in extreme environments, such as during the decomposition of mol. energetic materials, are still elusive. Here, we report on the original identification of the enol and keto isomers of oxy-s-triazine, as well as its deoxygenated derivative 1,3,5-triazine, formed in the photodecomposition processes of 1,3,5-trinitro-1,3,5-triazinane (RDX)-a mol. energetic material. The identification was facilitated by exploiting isomer-selective tunable photoionization reflectron time-of-flight mass spectrometry (PI-ReTOF-MS) in conjunction with quantum chem. calculations The present study reports the first exptl. evidence of an enol intermediate in the dissociation domain of a nitramine-based energetic material. Our investigations suggest that the enols like 1,3,5-triazine-2-ol could be the source of hydroxyl radicals, and their inclusion in the theor. models is important to understand the unprecedented chem. of explosive materials.
Journal of Physical Chemistry Letters published new progress about Adiabatic ionization potential. 123-39-7 belongs to class amides-buliding-blocks, name is N-Methylformamide, and the molecular formula is C2H5NO, Recommanded Product: N-Methylformamide.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics