Cooper, Geoffrey K. published the artcileAn ortho-directing effect in the nucleophilic aromatic substitution reactions of primary and secondary 2,4-dichloro- and 2,3,4-trichlorobenzamides with ethanethiolate, Computed Properties of 2447-79-2, the publication is Synthetic Communications (1995), 25(6), 899-906, database is CAplus.
The reactions of the primary and secondary 2,4-dichlorobenzamides and 2,3,4-trichlorobenzamides with potassium ethanethiolate in DMF were shown to proceed with a remarkable degree of ortho-regioselectivity. This effect was found to be absent using related tertiary amides as substrates. For example, treatment of 2,3,4-trichlorobenzamide with potassium ethanethiolate in DMF gave 3,4-dichloro-2-(ethylthio)benzamide.
Synthetic Communications published new progress about 2447-79-2. 2447-79-2 belongs to amides-buliding-blocks, auxiliary class Chloride,Amine,Benzene,Amide, name is 2,4-Dichlorobenzamide, and the molecular formula is C7H5Cl2NO, Computed Properties of 2447-79-2.
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