Pandey, Pragati published the artcileHydrosilylative reduction of primary amides to primary amines catalyzed by a terminal [Ni-OH] complex, HPLC of Formula: 1453-82-3, the publication is Chemical Communications (Cambridge, United Kingdom) (2021), 57(73), 9204-9207, database is CAplus and MEDLINE.
A terminal [Ni-OH] complex 1, supported by triflamide-functionalized NHC ligands, catalyzes the hydrosilylative reduction of a range of primary amides into primary amines in good to excellent yields under base-free conditions with key functional group tolerance. Catalyst 1 is also effective for the reduction of a variety of tertiary and secondary amides. In contrast to literature reports, the reactivity of 1 towards amide reduction follows an inverse trend, i.e., 1° amide > 3° amide > 2° amide. The reaction does not follow a usual dehydration pathway.
Chemical Communications (Cambridge, United Kingdom) published new progress about 1453-82-3. 1453-82-3 belongs to amides-buliding-blocks, auxiliary class Pyridine,Amine,Amide, name is Isonicotinamide, and the molecular formula is C6H6N2O, HPLC of Formula: 1453-82-3.
Referemce:
https://en.wikipedia.org/wiki/Amide,
Amide – an overview | ScienceDirect Topics