Yang, Long published the artcileElectrochemical B-H Nitrogenation: Access to Amino Acid and BODIPY-Labeled nido-Carboranes, Name: N,N-Diethylisonicotinamide, the publication is Angewandte Chemie, International Edition (2021), 60(3), 1482-1487, database is CAplus and MEDLINE.
Electrocatalyzed oxidative B-H nitrogenations of nido-carborane (nido-7,8-C2B9H12–) with N-heterocycles have been established, enabling the preparation of various N-substituted nido-carboranes without chem. oxidants or metal catalyst under ambient conditions. The electrolysis manifold occurred with high levels of efficiency as well as chemo- and position- selectivity, employing sustainable electricity as the sole oxidant. The strategy set the stage for a user-friendly access to novel amino acid and fluorogenic boron-dipyrrin (BODIPY)-labeled nido-carborane hybrids.
Angewandte Chemie, International Edition published new progress about 530-40-5. 530-40-5 belongs to amides-buliding-blocks, auxiliary class Pyridine,Amine,Amide, name is N,N-Diethylisonicotinamide, and the molecular formula is C9H5ClO4S, Name: N,N-Diethylisonicotinamide.
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