Chisca, Diana published the artcileFour Cu(II) coordination polymers with biocompatible isonicotinamide and picolinate ligands in interplay with anionic and neutral linkers, Application of Isonicotinamide, the publication is Inorganic Chemistry Communications (2021), 108864, database is CAplus.
Four Cu(II)-based neutral coordination polymers, 1D {[Cu(isonia)2(adi)(dmf)].0.5H2adi}n (1), 2D {[Cu(isonia)2(adi)](H2O.H2adi)}n (2), 1D {[Cu(pic)(CH3COO)(bpe)].H2O}n (3), and 2D [Cu2(pic)2(CH3COO)2(bpy)]n (4) with biocompatible mols.: isonicotinamide (isonia), pyridine-2-carboxylic (picolinic, Hpic) and adipic (H2adi) acids and 1,2-bis(4-pyridyl)-ethane (bpe) and 4,4′-bipyridine (bpy) as neutral linkers are reported. The polymer extension in 1 and 2 is reached via bidentate bridging adi anions with isonia ligands as single 1 and double 2 pillars. 1D and 2D coordination arrays are associated in elegant 3D H-bonded networks via interplay of robust amide(isonia)…amide(isonia) homosynthon and NH…O(COO–) side interactions. In 3 the pic residue coordinates in a chelate mode and forms the five-membered [Cu(pic)] corner fragment. The structure expansion occurs via bidentate-bridging bpe neutral linker registered in a coordination wire as different conformers thus providing long (Cu-bpe)6 crystallog. unique chain fragment. Oppositely, in 4 the pic residue acts in a bidentate chelate bridging mode and gives rise to the 2D coordination array. The bpy trapping between each two Cu(II) atoms, does not participate in further structure extension. The decisive impact of amido-group of isonia ligand in structure rigidification and retention of protic H2adi and water guest mols. is demonstrated. The gradual decrease of guest’s capacity correlates with an increased liphophilicity of 3 and 4 comparing with 1 and 2.
Inorganic Chemistry Communications published new progress about 1453-82-3. 1453-82-3 belongs to amides-buliding-blocks, auxiliary class Pyridine,Amine,Amide, name is Isonicotinamide, and the molecular formula is C6H6N2O, Application of Isonicotinamide.
Referemce:
https://en.wikipedia.org/wiki/Amide,
Amide – an overview | ScienceDirect Topics