Zhao, Yanbin published the artcileVanadium-catalyzed Oxidative Conversion of Primary Aromatic Alcohols into Amides and Nitriles with Molecular Oxygen, SDS of cas: 1453-82-3, the publication is Chemistry – An Asian Journal (2022), 17(11), e202200224, database is CAplus and MEDLINE.
Herein, a vanadium-based material V-N-C-700 was prepared via a simple and convenient method, and employed for liquid-phase catalytic ammoxidation of alcs. RCH2OH (R = n-Bu, Ph, pyridin-2-yl, etc.) with mol. oxygen. By using V-N-C-700/2-picolinic acid, primary aromatic alcs. were smoothly converted into the amides RC(O)NH2 and nitriles RCN in the presence of urea. The corresponding aldehydes RCHO are the key intermediates, and 2-picolinic acid could significantly enhance oxidation of alcs. into aldehydes. The amides were formed simultaneously along with nitriles, rather than only from nitriles via successive hydration. This work further expands non-noble metal catalysts for the preparation of amides and nitriles.
Chemistry – An Asian Journal published new progress about 1453-82-3. 1453-82-3 belongs to amides-buliding-blocks, auxiliary class Pyridine,Amine,Amide, name is Isonicotinamide, and the molecular formula is C20H19NO4, SDS of cas: 1453-82-3.
Referemce:
https://en.wikipedia.org/wiki/Amide,
Amide – an overview | ScienceDirect Topics