Tian, Wan-Fa published the artcileVisible-Light Photoredox-Catalyzed Iminyl Radical Formation by N-H Cleavage with Hydrogen Release and Its Application in Synthesis of Isoquinolines, Category: amides-buliding-blocks, the publication is Organic Letters (2018), 20(5), 1421-1425, database is CAplus and MEDLINE.
An unprecedented visible-light photoredox-catalyzed iminyl radical formation by N-H cleavage with H2 release has been developed. Its application in the synthesis of various isoquinolines, e.g., I, and related polyaromatics in high atom economy at ambient temperature by applying a photosensitizer, Acr+-Mes ClO4–, and a new cobalt catalyst, Co(dmgH)2(4-CONMe2Py)Cl is reported. Mechanistic investigations indicated that the generated iminyl radical initiates the cascade C-N/C-C bonds formation and the catalytic cycle occurs by a simultaneous oxidative as well as reductive quenching pathway.
Organic Letters published new progress about 530-40-5. 530-40-5 belongs to amides-buliding-blocks, auxiliary class Pyridine,Amine,Amide, name is N,N-Diethylisonicotinamide, and the molecular formula is C15H14O3, Category: amides-buliding-blocks.
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