Nitrogen-Doped Porous Molybdenum Carbide and Phosphide Hybrids on a Carbon Matrix as Highly Effective Electrocatalysts for the Hydrogen Evolution Reaction was written by Huang, Yichao;Ge, Jingxuan;Hu, Jun;Zhang, Jiangwei;Hao, Jian;Wei, Yongge. And the article was included in Advanced Energy Materials in 2018.Application of 2387-23-7 This article mentions the following:
The efficient evolution of hydrogen through electrocatalysis is considered a promising approach to the production of clean hydrogen fuel. Platinum (Pt)-based materials are regarded as the most active hydrogen evolution reaction (HER) catalysts. However, the low abundance and high cost of Pt hinders the large-scale application of these catalysts. Active, inexpensive, and earth-abundant electrocatalysts to replace Pt-based materials would be highly beneficial to the production of cost-effective hydrogen energy. Herein, a novel organoimido-derivatized heteropolyoxometalate, Mo4-CNP, is designed as a precursor for electrocatalysts of the HER. It is demonstrated that the carbon, nitrogen, and phosphorus sources derived from the Mo4-CNP mols. lead to in situ confined carburization, phosphorization, and chem. doping on an at. scale, thus forming nitrogen-doped porous molybdenum carbide and phosphide hybrids, which exhibit remarkable electrocatalytic activity for the HER. Such an organically functionalized polyoxometalate-assisted strategy described here provides a new perspective for the development of highly active non-noble metal electrocatalysts for hydrogen evolution. In the experiment, the researchers used many compounds, for example, 1,3-Dicyclohexylurea (cas: 2387-23-7Application of 2387-23-7).
1,3-Dicyclohexylurea (cas: 2387-23-7) belongs to amides. The solubilities of amides and esters are roughly comparable. Typically amides are less soluble than comparable amines and carboxylic acids since these compounds can both donate and accept hydrogen bonds. Tertiary amides, with the important exception of N,N-dimethylformamide, exhibit low solubility in water. Amides are not in general accessible by the direct condensation of amines with carboxylic acids for two reasons: first, both components are readily deactivated by a transfer of a proton from the acid to the amine and second, the hydroxy unit on the carbonyl of the acid is a relatively poor leaving group. Nevertheless, the formation of five- and six-membered rings is often surprisingly simple provided that other factors can be brought into play to assist in the condensation.Application of 2387-23-7
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics