Ohkubo, Katsutoshi published the artcileShape- and stereo-selective esterase activities of cross-linked polymers imprinted with a transition-state analogue for the hydrolysis of amino acid esters, Recommanded Product: N,N’-(Butane-1,4-diyl)diacrylamide, the main research area is nitrophenyl leucinate hydrolysis kinetics polymeric catalyst; histidyl polymer preparation catalyst hydrolysis leucinate; isokinetic relationship catalytic hydrolysis nitrophenyl leucinate.
Various cross-linked (with N,N’-ethylene (C2), butylene (C4), hexamethylene (C6), or decamethylene (C10)-bisacrylamide) polymer catalysts containing L-histidine and quaternary trimethylammonium groups were imprinted with a racemic transition-state analog of Ph 1-benzyloxycarbonyl-3-methylpentylphosphonate for the hydrolysis of p-nitrophenyl N-(benzyloxycarbonyl)-L (or D)-leucinate [Z-L (or D)-Leu-PNP]. Among these polymer catalysts, N,N’-C4-bisacrylamide-cross-linked polymer catalyst, which was copolymerized with styrene monomer, exhibited notable substrate-stereospecificity for the Z-L-Leu-PNP hydrolysis in the hydrolysis of enantiomeric L (or D)-N-protected [such as tert-butyloxycarbonyl (Boc-), acetyl (C2-), decanoyl (C10-) or benzyloxycarbonyl (Z-)] amino acid (Leu, Ala, or Phe) p-nitrophenyl esters in 10 volume % MeCN-Tris buffer (pH 7.15) at 30°C.
Journal of Molecular Catalysis A: Chemical published new progress about Amino acid esters Role: RCT (Reactant), RACT (Reactant or Reagent). 10405-38-6 belongs to class amides-buliding-blocks, name is N,N’-(Butane-1,4-diyl)diacrylamide, and the molecular formula is C10H16N2O2, Recommanded Product: N,N’-(Butane-1,4-diyl)diacrylamide.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics