Shen, Xianfu published the artcileCopper(I)-Catalyzed Cascade Cyclization to the Total Synthesis of Hexahydropyrroloindole Alkaloids: Flustramine B and Debromoflustramine B, Safety of (S)-2-Methylpropane-2-sulfinamide, the main research area is oxindole copper catalyst cascade cyclization one pot; hexahydropyrroleindole alkaloid preparation.
The total synthesis of two bioactive hexahydropyrroloindole (HPI) alkaloids beared a C3a tetrasubstituted stereocenters substituted by isopentenyl. This route was based on Cu-catalyzed cascade arylation-alkylation sequence in one-pot as a key step, provided Flustramine B and Debromoflustramine B with 9 steps in 37.6% and 31.1% overall yields, resp.
ChemistrySelect published new progress about Alkaloids Role: SPN (Synthetic Preparation), PREP (Preparation). 343338-28-3 belongs to class amides-buliding-blocks, name is (S)-2-Methylpropane-2-sulfinamide, and the molecular formula is C4H11NOS, Safety of (S)-2-Methylpropane-2-sulfinamide.
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics