Tiwari, Dilip published the artcileCopper complexes of imidazole-2-carbaldehyde N(4)-substituted thiosemicarbazones: synthesis, characterization and antimicrobial activity, COA of Formula: C5H10N2OS, the publication is Asian Journal of Chemistry (2016), 28(12), 2793-2797, database is CAplus.
Imidazole-2-carbaldehyde N(4)-pyrrolidinyl, N(4)-piperidinyl, N(4)-morpholinyl and N(4)-piperazinyl thiosemicarbazones and their copper(II) complexes were synthesized. The compounds were characterized by NMR, IR, UV-visible, ESR spectroscopy and ESI mass spectrometry. The stoichiometry, spectroscopic and mass spectrometry data indicates thiosemicarbazone coordination to Cu(II) in neutral form with NNS donors. The coordination spheres of the metal ion are completed by chlorine atoms in approx. square pyramidal geometry. The in vitro antimicrobial properties of the compounds in broth culture exhibited a moderate inhibitory effect on the microbial proliferation. Some copper(II) complexes exhibited a moderate inhibitory activity, better than that of the corresponding free thiosemicarbazone.
Asian Journal of Chemistry published new progress about 14294-10-1. 14294-10-1 belongs to amides-buliding-blocks, auxiliary class Morpholine,Thiourea,Amine,Amide, name is Morpholine-4-carbothioamide, and the molecular formula is C4H7BrO2, COA of Formula: C5H10N2OS.
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