Seidelmann, O. published the artcileCyclic voltammetric studies on N,N-disubstituted N’-ferrocenoylthioureas and their transition metal complexes, Recommanded Product: Morpholine-4-carbothioamide, the publication is Polyhedron (1998), 17(10), 1601-1610, database is CAplus.
The Fe(II)/Fe(III) redox potentials of N,N-disubstituted N’-ferrocenoylthioureas and the resp. ferrocene-1,1′-dicarbonic acid di-N,N-dialkyl-thioureids are shifted cathodically by complexation of Ni(II), Cu(II), Co(III), Mn(II), Pt(II) and Pd(II). The extent of the shift is more pronounced in the latter ligand class and reaches values up to -0.32 V. The N,N-disubstituted N’-ferrocenoylthioureas exhibit two redox processes in dichloromethane. A mechanistic scheme is proposed. Ferrocene-1,1′-dicarbonic acid di-N,N-dialkyl-thioureids decompose after oxidation in dichloromethane. In contrast, complexes of both ligand types contain quasireversibly oxidizable ferrocene subunits.
Polyhedron published new progress about 14294-10-1. 14294-10-1 belongs to amides-buliding-blocks, auxiliary class Morpholine,Thiourea,Amine,Amide, name is Morpholine-4-carbothioamide, and the molecular formula is C17H20ClN3, Recommanded Product: Morpholine-4-carbothioamide.
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