Bromilow, John published the artcileCarbon-13 substituent chemical shifts in the side-chain carbons of aromatic systems: the importance of π-polarization in determining chemical shifts, Name: 3-Methoxybenzothioamide, the publication is Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999) (1981), 753-9, database is CAplus.
13C substituent chem. shifts of the CO sites in the side chains of two-hundred and four m– and p-substituted benzenes were measured using a dual substituent parameter LFER, which showed that inductive effects are predominant. The reverse inductive contribution observed is explained in terms of a π-polarization mechanism. Critical support for this mechanism was obtained from an addnl. series where the CO group was complexed with Lewis acids. The concepts of extended and localized π-polarization are discussed.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999) published new progress about 64559-06-4. 64559-06-4 belongs to amides-buliding-blocks, auxiliary class Amine,Benzene,Amide,Ether, name is 3-Methoxybenzothioamide, and the molecular formula is C8H9NOS, Name: 3-Methoxybenzothioamide.
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