He, Peipei published the artcileHeterogeneous manganese-oxide-catalyzed successive cleavage and functionalization of alcohols to access amides and nitriles, Computed Properties of 1453-82-3, the publication is Chem (2022), 8(7), 1906-1927, database is CAplus.
Herein, a novel and efficient protocol that enables the direct synthesis of amides via heterogeneous manganese-oxide-catalyzed successive cleavage and amidation of C-C bonds in alcs was reported. A wide range of primary and secondary alcs., 1,2-diols, and even β-O-4 and β-1 lignin model compounds can undergo C-C bond cleavage smoothly to deliver one- or multiple-carbon shorter amides. Moreover, a slight modification of reaction conditions allows for the cleavage and cyanation of alcs. to access sterically hindered nitriles. Detailed characterizations and d. functional theory (DFT) calculations indicate that high sp. surface area, abundant oxygen vacancies, and moderate acid sites contribute to the high catalytic performance of the manganese oxides.
Chem published new progress about 1453-82-3. 1453-82-3 belongs to amides-buliding-blocks, auxiliary class Pyridine,Amine,Amide, name is Isonicotinamide, and the molecular formula is C6H6N2O, Computed Properties of 1453-82-3.
Referemce:
https://en.wikipedia.org/wiki/Amide,
Amide – an overview | ScienceDirect Topics