Poly(vinyl ketone)s by Controlled Boron Group Transfer Polymerization (BGTP) was written by Uehara, Kazuhiro;Wagner, Christine B.;Vogler, Thomas;Luftmann, Heinrich;Studer, Armido. And the article was included in Angewandte Chemie, International Edition in 2010.Application of 192436-83-2 This article mentions the following:
A novel method is presented for controlled radical polymerization of alkyl and aryl vinyl ketones. The process comprises an unprecedented boron group transfer reaction as the key step. Mass spectrometry studies support the suggested mechanism and elucidate possible termination processes. In the experiment, the researchers used many compounds, for example, 4-Bromo-N-methoxy-N-methylbenzamide (cas: 192436-83-2Application of 192436-83-2).
4-Bromo-N-methoxy-N-methylbenzamide (cas: 192436-83-2) belongs to amides. Amides can be viewed as a derivative of a carboxylic acid RC(=O)OH with the hydroxyl group –OH replaced by an amine group −NR′R″; or, equivalently, an acyl (alkanoyl) group RC(=O)− joined to an amine group. In simple aromatic amides, fragmentation occurs on both sides of the carbonyl group. If a hydrogen is available in N-substituted aromatic amides, it tends to migrate and form an aromatic amine and the loss of a ketene.Application of 192436-83-2
Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics