Recommanded Product: Diphenylmethanamine. Recently I am researching about H BOND-CLEAVAGE; N-C CLEAVAGE; SECONDARY AMIDES; CARBOXAMIDES; ACTIVATION, Saw an article supported by the National Research Foundation of Korea (NRF) – Korea Government (MSIT) [NRF-2021R1A2C1005169]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Joseph, D; Park, MS; Lee, S. The CAS is 91-00-9. Through research, I have a further understanding and discovery of Diphenylmethanamine
N-Acyl lactam amides, such as benzoylpyrrolidin-2-one, benzoylpiperidin-2-one, and benzoylazepan-2-one reacted with amines in the presence of DTBP and TBAI to afford the transamidated products in good yields. The reactions were conducted under aqueous conditions and good functional group tolerance was achieved. Both aliphatic and aromatic primary amines displayed good activity under metal-free conditions. A radical reaction pathway is proposed.
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Reference:
Amide – Wikipedia,
,Amide – an overview | ScienceDirect Topics