Category: 685-91-6

Amaral, Miriam C. S.; Moravia, Wagner G.; Lange, Lisete C. published an article in 2017, the title of the article was Characterization of residual organic compounds of aerobic degradation of landfill leachate.Synthetic Route of 685-91-6 And the article contains the following content:

The purpose of this article is to characterize and compare the residual COD of raw landfill leachate and its low and high mol. weight fractions before and after aerobic degradation process. The low and high mol. weight fractions (<10 kDa and >10 kDa, resp.) were obtained by the use of an ultrafiltration cell. Samples of the fractions with mol. weights 10 kDa, as well as the raw leachate, were characterized in terms of COD, protein, carbohydrate and lipid concentration and by biodegradability test. The compound identification of all samples was carried out using gas chromatog. coupled with mass spectrometry (GC/MS). The results show that the landfill leachate studied is constituted of approx. 60% of compounds with mol. weight <10 kDa. Approx. 80% of the compounds identified in the leachate had been degraded. This is an indication that most of the compounds that constitute the significant fraction of residual COD correspond to intermediate products and products of condensation of affluent compounds or had been generated during the degradation (SMP). Similar compounds were identified in all effluents of the degradation assay, suggesting the presence of SMP. These compounds, predominantly aliphatic and esters, are characterized by high mol. weight and probable refractory nature. The experimental process involved the reaction of N,N-Diethylacetamide(cas: 685-91-6).Synthetic Route of 685-91-6

The Article related to residual organic compound aerobic degradation landfill leachate, compounds identifications, smp, leachate, residual cod, Waste Treatment and Disposal: Chemical Treatment Of Aqueous Wastes and other aspects.Synthetic Route of 685-91-6

Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics

On March 5, 2021, Laurence, Christian; Mansour, Sergui; Vuluga, Daniela; Planchat, Aurelien; Legros, Julien published an article.Synthetic Route of 685-91-6 The title of the article was Hydrogen-Bond Acceptance of Solvents: A 19F Solvatomagnetic β1 Database to Replace Solvatochromic and Solvatovibrational Scales. And the article contained the following:

A variety of physicochem. properties and several hydrogen-bond donors have been used to define methods and to build scales aiming at measuring the hydrogen-bond acceptance of solvents. There is a great deal of confusion in these scales and methods. Solvatochromic, solvatocalorimetric, solvatovibrational, and 19F solvatomagnetic comparison methods are critically reviewed. Only two methods, the solvatomagnetic and the solvatocalorimetric ones, are able to yield reliable solvent hydrogen-bond acceptance scales. The solvatomagnetic β1 scale defined from the 19F chem. shift of 4-fluorophenol is extended to many solvents including ionic liquids and green solvents. The results for about 240 hydrogen-bond acceptor solvents are organized in a numerical β1 database. The comparison of β1 with solvatochromic scales highlights their shortcomings, in particular for the important class of amphiprotic solvents. Therefore, the use of the 19F solvatomagnetic comparison method and of the solvatomagnetic β1 scale is recommended in solvent effect studies. The experimental process involved the reaction of N,N-Diethylacetamide(cas: 685-91-6).Synthetic Route of 685-91-6

The Article related to solvent hydrogen bond acceptor solvatomagnetic scale database, Physical Organic Chemistry: Other Reactions, Processes, and Spectra and other aspects.Synthetic Route of 685-91-6

Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics

Nayaka, Swapna r.; Sabari, Anand j. v.; Shareef, Shaik mabu; Usha, N. s. published an article in 2020, the title of the article was Gas chromatography-mass spectroscopy [Gc-Ms] analysis and phytochemical screening for bioactive compounds in Caulerpapeltata(Greenalga).COA of Formula: C6H13NO And the article contains the following content:

Seaweeds (Marine macroalgae) area large group of marine organisms containing important phytochem. constituents with various biol. activities. They are potentially prolific sources of highly bioactivese condary metabolites, which manifest many of the rapeutic effects like anti-cancer, anti-oxidant, anti-inflammatory and anti-diabetic activities. Seaweeds are used by many Asian cultures for traditional medicine preparations The Caulerpapeltata was collected from Rameshwaram coastal area it was shade dried, made in to powder using standardized procedure to get Caulerpa peltata Methanolic Extract (CPME). The phytochems. and Gas Chromatog.-Mass Spectrometry (GC-MS) anal. was done on prepared CPME for identifying the bioactive compounds Phytochem. in vestigation suggests that the Caulerpa peltata exhibited the presence of phytochems. like Alkaloids, Carbohydrates, Phytosterols, Saponins and Diterpenes, which may contribute to its biol. activities. GC-MS anal. showed 28 variety of compounds, among which Dibutylphthalate, n-hexadecanoic acid, and 1,2-Benzenedic arboxylic acid was found in high percentage. The phytochem. studies and the compounds available in GC-MS showed that the Caulerpapeltata contain important bio active compounds, which may have anti-microbial, anti-fungal and anti-canceractivity. Further research is needed for finding its use in development of new pharmaceutical agent and its safe consumption by human for various health benefits. The experimental process involved the reaction of N,N-Diethylacetamide(cas: 685-91-6).COA of Formula: C6H13NO

The Article related to cauler papeltata bioactive compound phytochem gas chromatog mass spectroscopy, Microbial, Algal, and Fungal Biochemistry: Composition and Products and other aspects.COA of Formula: C6H13NO

Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics

Yang, Tianlong; Lu, Maojian; Lin, Zhaowei; Huang, Mingqiang; Cai, Shunyou published an article in 2019, the title of the article was Visible-light-promoted oxidation/condensation of benzyl alcohols with dialkylacetamides to cinnamides.Reference of N,N-Diethylacetamide And the article contains the following content:

Oxidative cross-coupling reactions of benzyl alcs. with N,N-dialkylacetamides were developed only employing oxygen as the terminal oxidant, efficiently providing a new, novel protocol for the construction of multifunctionalized cinnamides with the synergistic effects of KOH, organic photocatalyst eosin Y, and visible light irradiation at room temperature A broad substrate scope and mild reaction conditions are the prominent features of this transformation. The experimental process involved the reaction of N,N-Diethylacetamide(cas: 685-91-6).Reference of N,N-Diethylacetamide

The Article related to cinnamide preparation visible light promoted oxidation condensation reaction, oxidative cross coupling benzyl alc diarylacetamide organic photocatalyst, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: General and other aspects.Reference of N,N-Diethylacetamide

Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics

On September 19, 2017, Naya, Masami; Hamano, Yoshimi; Kokado, Kenta; Sada, Kazuki published an article.Formula: C6H13NO The title of the article was Organic Reaction as a Stimulus for Polymer Phase Separation. And the article contained the following:

Mol. design of stimuli-sensitive polymers has been attracting considerable interest of chemists because of their latent ability to achieve smart materials. Heat, light, pH, and chems. have been often utilized as a stimuli-inducing polymer phase transition from solution to aggregation and vice versa. In this report, as a new trigger for lower critical solution temperature (LCST)-type polymer phase transition, we introduce organic reaction of small organic mols., not to the polymer chain itself. The addition of the reactant for the “effector”, which can interact with the polymer chain for increasing the compatibility of the polymer chain with the media, caused a polymer phase separation, due to reduction of the solvation ability of the effector to the polymer chain. In other words, decrease of the “effector” concentration induced the polymer phase separation Within our knowledge, this is the first report to connect a polymer phase separation with organic reaction dynamics. This process will be the first step for the development of artificial allosteric enzyme mimics from a combination of a simple synthetic polymer and a product or reactant in organic reactions. The experimental process involved the reaction of N,N-Diethylacetamide(cas: 685-91-6).Formula: C6H13NO

The Article related to organic polymer stimuli sensitive phase separation, Chemistry of Synthetic High Polymers: Organic Addition Polymerization and other aspects.Formula: C6H13NO

Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics

On October 8, 2021, Chen, Yan-Ru; Chung, Hsiao-Wei; Tung, Shih-Huang published an article.Application In Synthesis of N,N-Diethylacetamide The title of the article was On the Formation Mechanism of Nonsolvent-Induced Porous Polylactide Electrospun Fibers. And the article contained the following:

Polylactide (PLA) fibers were electrospun from the solutions of PLA dissolved in the mixtures of its good and poor solvents, and the formation mechanism of the poor solvent-induced porous structure on the fibers was investigated. From a systematic study using the pairs of a variety of good/poor solvents for electrospinning, the conditions, specifically the solvent properties, for producing uniform fibers with controllable pores that appear not only on the surface but also throughout the fibers were proposed. The water miscibility of the good/poor solvents is crucial, which is because the ambient moisture that condenses during electrospinning plays an important role in the formation of the pores. Furthermore, the evaporation rate of the good/poor solvents is another key factor that affects the pore size and pore distribution on fibers because the solvent evaporation rate regulates the moisture condensation and the phase-separated scale that are closely related to fiber morphol. The principles generalized in this work can be applied to other low-polar polymers for controlling the porosity of fibers. In addition, this work demonstrates that the porous PLA fibers can be electrospun from low-toxic solvents and that with a large surface area and storage space provided by the pores, the PLA porous fibers are highly capable of adsorbing oils, with a capacity double that of the smooth counterpart. The experimental process involved the reaction of N,N-Diethylacetamide(cas: 685-91-6).Application In Synthesis of N,N-Diethylacetamide

The Article related to porous polylactide electrospun fiber, Textiles and Fibers: Fiber and Yarn Processing and Processing Materials and other aspects.Application In Synthesis of N,N-Diethylacetamide

Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics

On August 16, 2019, Yan, Dingyuan; Jiang, Heming; Sun, Wenxue; Wei, Wei; Zhao, Jing; Zhang, Xinhao; Wu, Yun-Dong published an article.HPLC of Formula: 685-91-6 The title of the article was Synthesis of Benzofurans and Benzoxazoles through a [3,3]-Sigmatropic Rearrangement: O-NHAc as a Multitasking Functional Group. And the article contained the following:

The synthesis of heterocycles relies heavily on diverse sigmatropic rearrangements triggered by the cleavage of X-Y (X, Y = C, O, N, S, I) bonds. However, a unified rearrangement approach for constructing heterocyclic libraries is highly desirable. Encouraged by computational anal. of [3,3]-sigmatropic rearrangements, we can now rapidly synthesize oxa-heterocycles by treating N-phenoxyacetamides (Ph-ONHAc) with compounds containing an sp-hybridized carbon. The generality of the process is illustrated by the late-stage diversification of natural products, including estrone and an approved drug. A combination of exptl. and computational studies revealed that the reactions proceed through a facile Claisen-like [3,3]-sigmatropic rearrangement/annulation process. The experimental process involved the reaction of N,N-Diethylacetamide(cas: 685-91-6).HPLC of Formula: 685-91-6

The Article related to synthesis benzofuran benzoxazole, sigmatropic rearrangement mol modeling, Heterocyclic Compounds (More Than One Hetero Atom): Oxazoles, Isoxazoles and other aspects.HPLC of Formula: 685-91-6

Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics

Sahoo, Basudev; Surkus, Annette-Enrica; Pohl, Marga-Martina; Radnik, Joerg; Schneider, Matthias; Bachmann, Stephan; Scalone, Michelangelo; Junge, Kathrin; Beller, Matthias published an article in 2017, the title of the article was A Biomass-Derived Non-Noble Cobalt Catalyst for Selective Hydrodehalogenation of Alkyl and (Hetero)Aryl Halides.Recommanded Product: N,N-Diethylacetamide And the article contains the following content:

Hydrodehalogenation is a straightforward approach for detoxifications of harmful anthropogenic organohalide-based pollutants, as well as removal of halide protecting groups used in multistep syntheses. A novel sustainable catalytic material was prepared from biowaste (chitosan) in combination with an earth-abundant cobalt salt. The heterogeneous catalyst was fully characterized by transmission electron microscope, X-ray diffraction, and XPS measurements, and successfully applied to hydrodehalogenation of alkyl and (hetero)aryl halides with broad scope (>40 examples) and excellent chemoselectivity using mol. hydrogen as a reductant. The general usefulness of this method is demonstrated by successful detoxification of non-degradable pesticides and fire retardants. Moreover, the potential of the catalyst as a deprotection tool is demonstrated in a multistep synthesis of (±)-peronatin B (alkaloid). The experimental process involved the reaction of N,N-Diethylacetamide(cas: 685-91-6).Recommanded Product: N,N-Diethylacetamide

The Article related to chitosan cobalt oxide catalyst hydrodehalogenation organohalide pollutant, chitosan, cobalt, hydrodehalogenation, hydrogen, non-noble metals, Catalysis, Reaction Kinetics, and Inorganic Reaction Mechanisms: Catalysts and other aspects.Recommanded Product: N,N-Diethylacetamide

Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics

On February 1, 2021, Ikeda, Yuko; Matsukawa, Yuko; Yonekura, Kyohei; Shirakawa, Eiji published an article.Electric Literature of 685-91-6 The title of the article was Amidoalkylation of Sulfonylheteroarenes with Alkylamides through a Radical Chain Mechanism. And the article contained the following:

In the presence of a substoichiometric amount of a tert-butoxy radical precursor and a base, alkylamides were found to be heteroarylated at their α-C-H bonds with sulfonylheteroarenes through homolytic aromatic substitution, where a radical chain is operative. The experimental process involved the reaction of N,N-Diethylacetamide(cas: 685-91-6).Electric Literature of 685-91-6

The Article related to amidoalkylation sulfonylheteroarene alkylamide radical chain preparation, amides role: rct (reactant), ract (reactant or reagent), amidoalkylation, radical reaction mechanism and other aspects.Electric Literature of 685-91-6

Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics

On November 16, 2017, Zhang, Bo; Wang, Lijun; Li, Rui; Rahman, Quazi Mahzabin; Shahbazi, Abolghasem published an article.Reference of N,N-Diethylacetamide The title of the article was Catalytic Conversion of Chlamydomonas to Hydrocarbons via the Ethanol-Assisted Liquefaction and Hydrotreating Processes. And the article contained the following:

Ethanol-assisted liquefaction followed by a hydrotreating process was applied to the microalgal biomass of Chlamydomonas. The intent of the research was to develop process technol. to convert microalgae into drop-in fuels. The operation conditions of the ethanol-assisted liquefaction were optimized using the following variables: reaction temperatures (200-290°), ethanol concentration (10-90 volume%), residence time (0.5-2 h), and the catalyst (SO42-/ZrO2). The application of a higher ethanol concentration and the solid acid enhanced extraction of algal lipids and transesterification. The highest liquid yield of 93.7% for catalytic liquefaction was obtained under the reaction conditions of (290°, 90 volume% ethanol, and 0.5 h). Hydrotreating of the liquid products generated via liquefying microalgae was conducted over a Mo2C/Biochar catalyst at 340° and 3.44 MPa hydrogen. The obtained products contained predominantly hydrocarbon mols. falling into the diesel range. The experimental process involved the reaction of N,N-Diethylacetamide(cas: 685-91-6).Reference of N,N-Diethylacetamide

The Article related to catalysis chlamydomonas hydrocarbon ethanol assisted liquefaction hydrotreating alternative fuel, Electrochemical, Radiational, and Thermal Energy Technology: Energy Sources and other aspects.Reference of N,N-Diethylacetamide

Referemce:
Amide – Wikipedia,
Amide – an overview | ScienceDirect Topics